The following series of screen shots show you how to
setup an email account in Outlook Express. This account is for james@example.com.
Firstly, choose 'Tools' and 'Accounts...'

Now choose 'Add' and 'Mail...'

Type in your name (e.g. Jack Jones)

Type in the email address you're setting up.

Type in the email server (mail.yourdomain.com) and your
ISPs SMTP (outgoing) mail server.

Type in the account name. Note: you must type the
username (e.g. james) followed by a percentage mark (%) followed by the
domain name (e.g. example.com). The password is just the password. Hit
'Next'.

Click on Finish. You've done it. Your account is set up.
